Abstract
Heterometallic Ln-Pt complexes, with the formula [Ln2Pt3(H2O)2(SAc)12] (Ln = Ho(1), Er(2); SAc = thioacetate), were synthesized. From natural bond orbital (NBO) and local orbital locator (LOL) analyses and X-ray absorption fine structure (XAFS) measurements, it was clear that the Ln-Pt interactions or electron polarization occurred. Butterfly-type hysteresis was observed for both 1 and 2. 1 and 2 underwent field-induced slow magnetic relaxation up to 4 K. These magnetic properties were induced by Ln-Pt electron polarization.
Original language | English |
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Pages (from-to) | 7144-7149 |
Number of pages | 6 |
Journal | Dalton Transactions |
Volume | 48 |
Issue number | 21 |
DOIs | |
Publication status | Published - 2019 |
ASJC Scopus subject areas
- Inorganic Chemistry