Lithium storage in Li 4Ti 5O 12 spinel: The full static picture from electron microscopy

Xia Lu; Liang Zhao; Xiaoqing He; Ruijuan Xiao; Lin Gu; Yong Sheng Hu; Hong Li; Zhaoxiang Wang; Xiaofeng Duan; Liquan Chen; Joachim Maier; Yuichi Ikuhara

doi:10.1002/adma.201200450

Lithium storage in Li ₄Ti ₅O ₁₂ spinel: The full static picture from electron microscopy

Xia Lu, Liang Zhao, Xiaoqing He, Ruijuan Xiao, Lin Gu, Yong Sheng Hu, Hong Li, Zhaoxiang Wang, Xiaofeng Duan, Liquan Chen, Joachim Maier, Yuichi Ikuhara

Research output: Contribution to journal › Article

221 Citations (Scopus)

Abstract

The full static picture of Li storage in Li ₄Ti ₅O ₁₂ is derived using the latest spherical aberration-corrected scanning transmission electron microscopy and first-principles calculations. The accommodation of the additional Li ⁺ is directly visualized and the distribution of electrons introduced by lithium insertion deduced. Moreover, Li ₄Ti ₅O ₁₂ is found to transform into Li ₇Ti ₅O ₁₂ on lithiation by developing a dislocation-free coherent hetero-interface.

Original language	English
Pages (from-to)	3233-3238
Number of pages	6
Journal	Advanced Materials
Volume	24
Issue number	24
DOIs	https://doi.org/10.1002/adma.201200450
Publication status	Published - 2012 Jun 26

Keywords

interfaces
lithium-ion batteries
scanning transmission electron microscopy

ASJC Scopus subject areas

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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10.1002/adma.201200450

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Lu, X., Zhao, L., He, X., Xiao, R., Gu, L., Hu, Y. S., Li, H., Wang, Z., Duan, X., Chen, L., Maier, J., & Ikuhara, Y. (2012). Lithium storage in Li ₄Ti ₅O ₁₂ spinel: The full static picture from electron microscopy. Advanced Materials, 24(24), 3233-3238. https://doi.org/10.1002/adma.201200450

Lithium storage in Li ₄Ti ₅O ₁₂ spinel : The full static picture from electron microscopy. / Lu, Xia; Zhao, Liang; He, Xiaoqing; Xiao, Ruijuan; Gu, Lin; Hu, Yong Sheng; Li, Hong; Wang, Zhaoxiang; Duan, Xiaofeng; Chen, Liquan; Maier, Joachim; Ikuhara, Yuichi.

In: Advanced Materials, Vol. 24, No. 24, 26.06.2012, p. 3233-3238.

Research output: Contribution to journal › Article

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