Lithium aluminum nitride, Li3AlN2 as a lithium solid electrolyte

H. Yamane, S. Kikkawa, M. Koizumi

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

Single phase of Li3AlN2 was prepared from the mixture of Li3N/AlN = 1.2 to 1.5 in molar ratio at 700°C and at 900°C. It crystalizes in the cubic system derived from antifluorite-type structure having the lattice parameter a = 9.470 A ̊. It is a pure ionic conductor having conductivity of 5 × 10-8 ω-1 cm-1 at room temperature and an activation energy of 52 kJ/ mol. Its decomposition voltage was 0.85 V at 104°C. The TiS2/Li3AlN2/Li cell could be discharged at a constant current of 45 μA/cm2 at 104°C.

Original languageEnglish
Pages (from-to)51-54
Number of pages4
JournalSolid State Ionics
Volume15
Issue number1
DOIs
Publication statusPublished - 1985 Feb
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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