Linking [FeIII3] triangles with “double-headed”phenolic oximes

K. Mason; J. Chang; E. Garlatti; A. Prescimone; S. Yoshii; H. Nojiri; J. Schnack; P. A. Tasker; S. Carretta; E. K. Brechin

doi:10.1039/c1cc11146a

Linking [Fe^III₃] triangles with “double-headed”phenolic oximes

K. Mason, J. Chang, E. Garlatti, A. Prescimone, S. Yoshii, H. Nojiri, J. Schnack, P. A. Tasker, S. Carretta, E. K. Brechin

Institute for Materials Research (IMR)

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The use of “double-headed” phenolic oximes produces a trigonal antiprismatic [Fe^III₃]₂ cluster with an “internal cavity” filled with an additional Fe³⁺ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

Original language	English
Pages (from-to)	6018-6020
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	21
DOIs	https://doi.org/10.1039/c1cc11146a
Publication status	Published - 2011 May 16

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc11146a

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abstract = "The use of “double-headed” phenolic oximes produces a trigonal antiprismatic [FeIII3]2 cluster with an “internal cavity” filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.",

author = "K. Mason and J. Chang and E. Garlatti and A. Prescimone and S. Yoshii and H. Nojiri and J. Schnack and Tasker, {P. A.} and S. Carretta and Brechin, {E. K.}",

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AU - Mason, K.

AU - Chang, J.

AU - Garlatti, E.

AU - Prescimone, A.

AU - Yoshii, S.

AU - Nojiri, H.

AU - Schnack, J.

AU - Tasker, P. A.

AU - Carretta, S.

AU - Brechin, E. K.

PY - 2011/5/16

Y1 - 2011/5/16

N2 - The use of “double-headed” phenolic oximes produces a trigonal antiprismatic [FeIII3]2 cluster with an “internal cavity” filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

AB - The use of “double-headed” phenolic oximes produces a trigonal antiprismatic [FeIII3]2 cluster with an “internal cavity” filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

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JF - Chemical Communications

SN - 1359-7345

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Linking [Fe^III₃] triangles with “double-headed”phenolic oximes

Abstract

ASJC Scopus subject areas

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