Linking [FeIII3] triangles with “double-headed”phenolic oximes

K. Mason, J. Chang, E. Garlatti, A. Prescimone, S. Yoshii, H. Nojiri, J. Schnack, P. A. Tasker, S. Carretta, E. K. Brechin

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The use of “double-headed” phenolic oximes produces a trigonal antiprismatic [FeIII3]2 cluster with an “internal cavity” filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

Original languageEnglish
Pages (from-to)6018-6020
Number of pages3
JournalChemical Communications
Volume47
Issue number21
DOIs
Publication statusPublished - 2011 May 16

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'Linking [Fe<sup>III</sup><sub>3</sub>] triangles with “double-headed”phenolic oximes'. Together they form a unique fingerprint.

Cite this