TY - JOUR
T1 - Linkage-isomerization and charge-transfer in the formation of iron mixed valence complexes, (n-C3H7)4N[Fe IIFeIII(dto)3] (dto C2O 2S2) and (n-C4H9) 4N[FeIIFeIII(mto)3] (mto C 2O3S)
AU - Kagesawa, K.
AU - Kida, N.
AU - Ono, Y.
AU - Enomoto, M.
AU - Kojima, N.
N1 - Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 2010
Y1 - 2010
N2 - In iron mixed-valence complex, (n-C3H7) 4N[FeIIFeIII(dto)3] (dto C 2O2S2), the linkage isomerisation and charge-transfer between FeII FeIII occur in the precipitation process. We succeeded the suppression of linkage-isomerization and charge-transfer in the formation process of (n-C3H7) 4N[FeIIFeIII(dto)3] by the synthesis on low temperature condition and the selection of solvent. Moreover, we have found that the charge transfer occurs in the formation of (n-C4H 9)4N[FeIIFeIII(mto)3] (mto C2O3S) without linkage-isomerization.
AB - In iron mixed-valence complex, (n-C3H7) 4N[FeIIFeIII(dto)3] (dto C 2O2S2), the linkage isomerisation and charge-transfer between FeII FeIII occur in the precipitation process. We succeeded the suppression of linkage-isomerization and charge-transfer in the formation process of (n-C3H7) 4N[FeIIFeIII(dto)3] by the synthesis on low temperature condition and the selection of solvent. Moreover, we have found that the charge transfer occurs in the formation of (n-C4H 9)4N[FeIIFeIII(mto)3] (mto C2O3S) without linkage-isomerization.
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U2 - 10.1088/1742-6596/217/1/012034
DO - 10.1088/1742-6596/217/1/012034
M3 - Conference article
AN - SCOPUS:77954688473
VL - 217
JO - Journal of Physics: Conference Series
JF - Journal of Physics: Conference Series
SN - 1742-6588
IS - 1
M1 - 012034
T2 - International Conference on the Applications of the Mossbauer Effect, ICAME 2009
Y2 - 19 July 2009 through 24 July 2009
ER -