Linkage-isomerization and charge-transfer in the formation of iron mixed valence complexes, (n-C3H7)4N[Fe IIFeIII(dto)3] (dto C2O 2S2) and (n-C4H9) 4N[FeIIFeIII(mto)3] (mto C 2O3S)

K. Kagesawa; N. Kida; Y. Ono; M. Enomoto; N. Kojima

doi:10.1088/1742-6596/217/1/012034

Linkage-isomerization and charge-transfer in the formation of iron mixed valence complexes, (n-C₃H₇)₄N[Fe ^IIFe^III(dto)₃] (dto C₂O ₂S₂) and (n-C₄H₉) ₄N[Fe^IIFe^III(mto)₃] (mto C ₂O₃S)

K. Kagesawa, N. Kida, Y. Ono, M. Enomoto, N. Kojima

SCI - Chemistry

Research output: Contribution to journal › Conference article › peer-review

Abstract

In iron mixed-valence complex, (n-C₃H₇) ₄N[Fe^IIFe^III(dto)₃] (dto C ₂O₂S₂), the linkage isomerisation and charge-transfer between Fe^II Fe^III occur in the precipitation process. We succeeded the suppression of linkage-isomerization and charge-transfer in the formation process of (n-C₃H₇) ₄N[Fe^IIFe^III(dto)₃] by the synthesis on low temperature condition and the selection of solvent. Moreover, we have found that the charge transfer occurs in the formation of (n-C₄H ₉)₄N[Fe^IIFe^III(mto)₃] (mto C₂O₃S) without linkage-isomerization.

Original language	English
Article number	012034
Journal	Journal of Physics: Conference Series
Volume	217
Issue number	1
DOIs	https://doi.org/10.1088/1742-6596/217/1/012034
Publication status	Published - 2010
Event	International Conference on the Applications of the Mossbauer Effect, ICAME 2009 - Vienna, Austria Duration: 2009 Jul 19 → 2009 Jul 24

ASJC Scopus subject areas

Physics and Astronomy(all)

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Linkage-isomerization and charge-transfer in the formation of iron mixed valence complexes, (n-C₃H₇)₄N[Fe ^IIFe^III(dto)₃] (dto C₂O ₂S₂) and (n-C₄H₉) ₄N[Fe^IIFe^III(mto)₃] (mto C ₂O₃S). / Kagesawa, K.; Kida, N.; Ono, Y.; Enomoto, M.; Kojima, N.

In: Journal of Physics: Conference Series, Vol. 217, No. 1, 012034, 2010.

Research output: Contribution to journal › Conference article › peer-review

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title = "Linkage-isomerization and charge-transfer in the formation of iron mixed valence complexes, (n-C3H7)4N[Fe IIFeIII(dto)3] (dto C2O 2S2) and (n-C4H9) 4N[FeIIFeIII(mto)3] (mto C 2O3S)",

abstract = "In iron mixed-valence complex, (n-C3H7) 4N[FeIIFeIII(dto)3] (dto C 2O2S2), the linkage isomerisation and charge-transfer between FeII FeIII occur in the precipitation process. We succeeded the suppression of linkage-isomerization and charge-transfer in the formation process of (n-C3H7) 4N[FeIIFeIII(dto)3] by the synthesis on low temperature condition and the selection of solvent. Moreover, we have found that the charge transfer occurs in the formation of (n-C4H 9)4N[FeIIFeIII(mto)3] (mto C2O3S) without linkage-isomerization.",

author = "K. Kagesawa and N. Kida and Y. Ono and M. Enomoto and N. Kojima",

note = "Copyright: Copyright 2018 Elsevier B.V., All rights reserved.; International Conference on the Applications of the Mossbauer Effect, ICAME 2009 ; Conference date: 19-07-2009 Through 24-07-2009",

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T1 - Linkage-isomerization and charge-transfer in the formation of iron mixed valence complexes, (n-C3H7)4N[Fe IIFeIII(dto)3] (dto C2O 2S2) and (n-C4H9) 4N[FeIIFeIII(mto)3] (mto C 2O3S)

AU - Kagesawa, K.

AU - Kida, N.

AU - Ono, Y.

AU - Enomoto, M.

AU - Kojima, N.

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N2 - In iron mixed-valence complex, (n-C3H7) 4N[FeIIFeIII(dto)3] (dto C 2O2S2), the linkage isomerisation and charge-transfer between FeII FeIII occur in the precipitation process. We succeeded the suppression of linkage-isomerization and charge-transfer in the formation process of (n-C3H7) 4N[FeIIFeIII(dto)3] by the synthesis on low temperature condition and the selection of solvent. Moreover, we have found that the charge transfer occurs in the formation of (n-C4H 9)4N[FeIIFeIII(mto)3] (mto C2O3S) without linkage-isomerization.

AB - In iron mixed-valence complex, (n-C3H7) 4N[FeIIFeIII(dto)3] (dto C 2O2S2), the linkage isomerisation and charge-transfer between FeII FeIII occur in the precipitation process. We succeeded the suppression of linkage-isomerization and charge-transfer in the formation process of (n-C3H7) 4N[FeIIFeIII(dto)3] by the synthesis on low temperature condition and the selection of solvent. Moreover, we have found that the charge transfer occurs in the formation of (n-C4H 9)4N[FeIIFeIII(mto)3] (mto C2O3S) without linkage-isomerization.

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