In iron mixed-valence complex, (n-C3H7) 4N[FeIIFeIII(dto)3] (dto C 2O2S2), the linkage isomerisation and charge-transfer between FeII FeIII occur in the precipitation process. We succeeded the suppression of linkage-isomerization and charge-transfer in the formation process of (n-C3H7) 4N[FeIIFeIII(dto)3] by the synthesis on low temperature condition and the selection of solvent. Moreover, we have found that the charge transfer occurs in the formation of (n-C4H 9)4N[FeIIFeIII(mto)3] (mto C2O3S) without linkage-isomerization.
|Journal||Journal of Physics: Conference Series|
|Publication status||Published - 2010|
|Event||International Conference on the Applications of the Mossbauer Effect, ICAME 2009 - Vienna, Austria|
Duration: 2009 Jul 19 → 2009 Jul 24
ASJC Scopus subject areas
- Physics and Astronomy(all)