Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet

Shiori Hino; Moe Maeda; Kei Yamashita; Yumiko Kataoka; Motohiro Nakano; Tomoo Yamamura; Hiroyuki Nojiri; Maiko Kofu; Osamu Yamamuro; Takashi Kajiwara

doi:10.1039/c2dt32812g

Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet

Shiori Hino, Moe Maeda, Kei Yamashita, Yumiko Kataoka, Motohiro Nakano, Tomoo Yamamura, Hiroyuki Nojiri, Maiko Kofu, Osamu Yamamuro, Takashi Kajiwara

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Linear Zn(ii)-Ce(iii)-Zn(ii) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground ²F_5/2 state of Ce(iii) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other five oxygens as equatorial donors.

Original language	English
Pages (from-to)	2683-2686
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	8
DOIs	https://doi.org/10.1039/c2dt32812g
Publication status	Published - 2013 Feb 28

ASJC Scopus subject areas

Inorganic Chemistry

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Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet. / Hino, Shiori; Maeda, Moe; Yamashita, Kei; Kataoka, Yumiko; Nakano, Motohiro; Yamamura, Tomoo; Nojiri, Hiroyuki; Kofu, Maiko; Yamamuro, Osamu; Kajiwara, Takashi.

In: Dalton Transactions, Vol. 42, No. 8, 28.02.2013, p. 2683-2686.

Research output: Contribution to journal › Article › peer-review

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author = "Shiori Hino and Moe Maeda and Kei Yamashita and Yumiko Kataoka and Motohiro Nakano and Tomoo Yamamura and Hiroyuki Nojiri and Maiko Kofu and Osamu Yamamuro and Takashi Kajiwara",

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AU - Kataoka, Yumiko

AU - Nakano, Motohiro

AU - Yamamura, Tomoo

AU - Nojiri, Hiroyuki

AU - Kofu, Maiko

AU - Yamamuro, Osamu

AU - Kajiwara, Takashi

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Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet

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