Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet

Shiori Hino, Moe Maeda, Kei Yamashita, Yumiko Kataoka, Motohiro Nakano, Tomoo Yamamura, Hiroyuki Nojiri, Maiko Kofu, Osamu Yamamuro, Takashi Kajiwara

Research output: Contribution to journalArticlepeer-review

54 Citations (Scopus)

Abstract

Linear Zn(ii)-Ce(iii)-Zn(ii) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground 2F5/2 state of Ce(iii) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other five oxygens as equatorial donors.

Original languageEnglish
Pages (from-to)2683-2686
Number of pages4
JournalDalton Transactions
Volume42
Issue number8
DOIs
Publication statusPublished - 2013 Feb 28

ASJC Scopus subject areas

  • Inorganic Chemistry

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