Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet

Shiori Hino; Moe Maeda; Kei Yamashita; Yumiko Kataoka; Motohiro Nakano; Tomoo Yamamura; Hiroyuki Nojiri; Maiko Kofu; Osamu Yamamuro; Takashi Kajiwara

doi:10.1039/c2dt32812g

Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet

Shiori Hino, Moe Maeda, Kei Yamashita, Yumiko Kataoka, Motohiro Nakano, Tomoo Yamamura, Hiroyuki Nojiri, Maiko Kofu, Osamu Yamamuro, Takashi Kajiwara

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

Linear Zn(ii)-Ce(iii)-Zn(ii) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground ²F_5/2 state of Ce(iii) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other five oxygens as equatorial donors.

Original language	English
Pages (from-to)	2683-2686
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	8
DOIs	https://doi.org/10.1039/c2dt32812g
Publication status	Published - 2013 Feb 28

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet",

abstract = "Linear Zn(ii)-Ce(iii)-Zn(ii) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground 2F5/2 state of Ce(iii) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other five oxygens as equatorial donors.",

author = "Shiori Hino and Moe Maeda and Kei Yamashita and Yumiko Kataoka and Motohiro Nakano and Tomoo Yamamura and Hiroyuki Nojiri and Maiko Kofu and Osamu Yamamuro and Takashi Kajiwara",

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T1 - Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet

AU - Hino, Shiori

AU - Maeda, Moe

AU - Yamashita, Kei

AU - Kataoka, Yumiko

AU - Nakano, Motohiro

AU - Yamamura, Tomoo

AU - Nojiri, Hiroyuki

AU - Kofu, Maiko

AU - Yamamuro, Osamu

AU - Kajiwara, Takashi

PY - 2013/2/28

Y1 - 2013/2/28

N2 - Linear Zn(ii)-Ce(iii)-Zn(ii) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground 2F5/2 state of Ce(iii) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other five oxygens as equatorial donors.

AB - Linear Zn(ii)-Ce(iii)-Zn(ii) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground 2F5/2 state of Ce(iii) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other five oxygens as equatorial donors.

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JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

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ER -

Linear trinuclear Zn(ii)-Ce(iii)-Zn(ii) complex which behaves as a single-molecule magnet

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