Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr 6O 4(OH) 4(BDC) 6 (UiO-66)

Maw Lin Foo, Satoshi Horike, Tomohiro Fukushima, Yuh Hijikata, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa

Research output: Contribution to journalArticle

115 Citations (Scopus)

Abstract

By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr 6O 4(OH) 4(BDC-SO 3H) 1.1(BDC) 4.9 possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr 6O 4(OH) 4(BDC) 6.

Original languageEnglish
Pages (from-to)13791-13794
Number of pages4
JournalDalton Transactions
Volume41
Issue number45
DOIs
Publication statusPublished - 2012 Dec 7
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry

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