Lewis acid-catalyzed hydrometalation and carbometalation of unactivated alkynes

Naoki Asao, Yoshinori Yamamoto

    Research output: Contribution to journalArticle

    63 Citations (Scopus)

    Abstract

    Hydrosilylation, hydrostannation, carbosilylation, and carbostannation of unactivated alkynes with organosilanes, or organostannanes proceed effectively in the presence of catalytic amounts of Lewis acids to produce the corresponding vinylsilyl or vinylstannyl compounds in a highly regio- and stereoselective way. Although it is well known that transition metal catalyzed hydrometalations and carbometalations, in general, proceed in a cis-manner, the Lewis acid-catalyzed reactions proceed in a trans-manner exclusively. The coordination of a triple bond to Lewis acids is proposed as a key step for the Lewis acid catalyzed reactions.

    Original languageEnglish
    Pages (from-to)1071-1087
    Number of pages17
    JournalBulletin of the Chemical Society of Japan
    Volume73
    Issue number5
    DOIs
    Publication statusPublished - 2000 May 1

    ASJC Scopus subject areas

    • Chemistry(all)

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