Lattice relaxation of monosize CeO2-x nanocrystalline particles

S. Tsunekawa, R. Sahara, Y. Kawazoe, K. Ishikawa

Research output: Contribution to journalArticlepeer-review

118 Citations (Scopus)

Abstract

Lattice constants in monosize CeO2-x nanocrystalline particles increase with decreasing particle size. This phenomenon called lattice relaxation is well explained by the model that the number of surface oxygen is reduced to half and its nominal valence is not -2 or -0.5 but -1. This suggests that all the surface oxygen form O22- species in the nanocrystallites.

Original languageEnglish
Pages (from-to)53-56
Number of pages4
JournalApplied Surface Science
Volume152
Issue number1
DOIs
Publication statusPublished - 1999 Nov 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Physics and Astronomy(all)
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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