Large anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex

Qiong Ye, Hong Zhao, Zhi Rong Qu, Da Wei Fu, Ren Gen Xiong, Yi Ping Cui, Tomoyuki Akutagawa, Philip Wai Hong Chan, Takayoshi Nakamura

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

(Chemical Equation Presented) Different directions: Huge and permanent anisotropy (see picture, left) was observed in an olefin copper complex (see structural formula, right). This phenomenon is likely due to weak D⋯Br interactions in the crystal.

Original languageEnglish
Pages (from-to)6852-6856
Number of pages5
JournalAngewandte Chemie - International Edition
Volume46
Issue number36
DOIs
Publication statusPublished - 2007 Sep 24
Externally publishedYes

Keywords

  • Copper
  • Deuterium
  • Dielectric constant
  • Isotopic effects
  • X-ray diffraction

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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    Ye, Q., Zhao, H., Qu, Z. R., Fu, D. W., Xiong, R. G., Cui, Y. P., Akutagawa, T., Chan, P. W. H., & Nakamura, T. (2007). Large anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex. Angewandte Chemie - International Edition, 46(36), 6852-6856. https://doi.org/10.1002/anie.200700629