Langmuir-Blodgett films of molecular conductors based on alkylTCNQ derivatives

T. Nakamura; T. Konuma; Tomoyuki Akutagawa; H. Tachibana; R. Azumi; M. Matsumoto; H. Isotalo; S. Horiuchi; H. Yamochi; G. Saito

doi:10.1016/S0379-6779(97)80931-9

Langmuir-Blodgett films of molecular conductors based on alkylTCNQ derivatives

T. Nakamura, T. Konuma, Tomoyuki Akutagawa, H. Tachibana, R. Azumi, M. Matsumoto, H. Isotalo, S. Horiuchi, H. Yamochi, G. Saito

Research output: Contribution to journal › Conference article › peer-review

Abstract

The charge transfer properties of alkylTCNQ derivatives in the LB films of molecular conductors were examined. TMTTF, OMTTF and BEDOTTF were adopted as donors to form charge transfer complexes with C₁₀ TCNQ or C₁₄TCNQ. The degree of charge transfer of the alkylTCNQ in the LB films could be controlled from nearly neutral to fully ionic state by adopting appropriate donors for the counterpart. OMTTF-C₁₀TCNQ formed a neutral complex which is located near the neutral-ionic boundary and is expected to be a candidate to realise neutral-ionic phase transition in the LB films.

Original language	English
Pages (from-to)	1843-1844
Number of pages	2
Journal	Synthetic Metals
Volume	86
Issue number	1 -3 pt 3
DOIs	https://doi.org/10.1016/S0379-6779(97)80931-9
Publication status	Published - 1997 Jan 1
Externally published	Yes
Event	Proceedings of the 1996 International Conference on Science and Technology of Synthetic Metals, ICSM'96. Part 3 (of 3) - Snowbird, UT, USA Duration: 1996 Jul 28 → 1996 Aug 2

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/S0379-6779(97)80931-9

Cite this

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title = "Langmuir-Blodgett films of molecular conductors based on alkylTCNQ derivatives",

abstract = "The charge transfer properties of alkylTCNQ derivatives in the LB films of molecular conductors were examined. TMTTF, OMTTF and BEDOTTF were adopted as donors to form charge transfer complexes with C10 TCNQ or C14TCNQ. The degree of charge transfer of the alkylTCNQ in the LB films could be controlled from nearly neutral to fully ionic state by adopting appropriate donors for the counterpart. OMTTF-C10TCNQ formed a neutral complex which is located near the neutral-ionic boundary and is expected to be a candidate to realise neutral-ionic phase transition in the LB films.",

author = "T. Nakamura and T. Konuma and Tomoyuki Akutagawa and H. Tachibana and R. Azumi and M. Matsumoto and H. Isotalo and S. Horiuchi and H. Yamochi and G. Saito",

year = "1997",

month = jan,

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doi = "10.1016/S0379-6779(97)80931-9",

language = "English",

volume = "86",

pages = "1843--1844",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "1 -3 pt 3",

note = "Proceedings of the 1996 International Conference on Science and Technology of Synthetic Metals, ICSM'96. Part 3 (of 3) ; Conference date: 28-07-1996 Through 02-08-1996",

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TY - JOUR

T1 - Langmuir-Blodgett films of molecular conductors based on alkylTCNQ derivatives

AU - Nakamura, T.

AU - Konuma, T.

AU - Akutagawa, Tomoyuki

AU - Tachibana, H.

AU - Azumi, R.

AU - Matsumoto, M.

AU - Isotalo, H.

AU - Horiuchi, S.

AU - Yamochi, H.

AU - Saito, G.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The charge transfer properties of alkylTCNQ derivatives in the LB films of molecular conductors were examined. TMTTF, OMTTF and BEDOTTF were adopted as donors to form charge transfer complexes with C10 TCNQ or C14TCNQ. The degree of charge transfer of the alkylTCNQ in the LB films could be controlled from nearly neutral to fully ionic state by adopting appropriate donors for the counterpart. OMTTF-C10TCNQ formed a neutral complex which is located near the neutral-ionic boundary and is expected to be a candidate to realise neutral-ionic phase transition in the LB films.

AB - The charge transfer properties of alkylTCNQ derivatives in the LB films of molecular conductors were examined. TMTTF, OMTTF and BEDOTTF were adopted as donors to form charge transfer complexes with C10 TCNQ or C14TCNQ. The degree of charge transfer of the alkylTCNQ in the LB films could be controlled from nearly neutral to fully ionic state by adopting appropriate donors for the counterpart. OMTTF-C10TCNQ formed a neutral complex which is located near the neutral-ionic boundary and is expected to be a candidate to realise neutral-ionic phase transition in the LB films.

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U2 - 10.1016/S0379-6779(97)80931-9

DO - 10.1016/S0379-6779(97)80931-9

M3 - Conference article

VL - 86

SP - 1843

EP - 1844

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

IS - 1 -3 pt 3

T2 - Proceedings of the 1996 International Conference on Science and Technology of Synthetic Metals, ICSM'96. Part 3 (of 3)

Y2 - 28 July 1996 through 2 August 1996

ER -

Langmuir-Blodgett films of molecular conductors based on alkylTCNQ derivatives

Abstract

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