Lactone-based liquid electrolytes for fluoride shuttle batteries

Mitsuo Kawasaki, Ken Ichi Morigaki, Gentaro Kano, Hirofumi Nakamoto, Reiji Takekawa, Junichi Kawamura, Taketoshi Minato, Takeshi Abe, Zempachi Ogumi

Research output: Contribution to journalArticlepeer-review

Abstract

Rechargeable secondary batteries operating through fluoride-ion shuttling between the positive and negative electrodes, referred to as fluoride shuttle batteries (FSBs), offer a potentially promising solution to overcoming the energy-density limitations of current lithium-ion battery systems. However, there are many technical issues that need to be resolved to achieve high-quality fluoride-carrying electrolytes and ensure reversible transformations between a metal and its fluoride counterpart at both electrodes. Here, we introduce novel lactone-based liquid electrolytes consisting either of CsF or KF, which are prepared by a solvent substitution method. Although the maximum fluoride-ion concentration achieved by the method is approximately 0.05 M, these systems behave as strong electrolytes where CsF(KF) is almost fully dissociated into Cs+(K+) and F ions to give a maximum ionic conductivity of 0.8 mS.cm−1. Hence, the solvent supports electrochemically active fluoride ions that can drive reversible metal/metal-fluoride transformations at room temperature for a wide range of metal electrodes. However, irreversible reductive reactions of the solvent, also promoted by the fluoride ions, limit currently the negative potential window to approximately −1.5 V vs the standard hydrogen electrode.

Original languageEnglish
Article number010529
JournalJournal of the Electrochemical Society
Volume168
Issue number1
DOIs
Publication statusPublished - 2021 Jan

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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