Why do higher order cyanocuprates often show higher reactivity than the classical Gilman reagent? Computational theoretical studies suggest that the key lies in the properties of the bridging [LiCNLi]+ moiety in the cuprate (see scheme).
|Number of pages||4|
|Journal||Angewandte Chemie - International Edition|
|Publication status||Published - 2001 May 18|
- Density functional calculations
- Reaction mechanisms
ASJC Scopus subject areas