Kinetic reactivity of "higher order cuprates" in SN2 alkylation reactions

Eiichi Nakamura, Masahiro Yamanaka, Naohiko Yoshikai, Seiji Mori

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Why do higher order cyanocuprates often show higher reactivity than the classical Gilman reagent? Computational theoretical studies suggest that the key lies in the properties of the bridging [LiCNLi]+ moiety in the cuprate (see scheme).

Original languageEnglish
Pages (from-to)1935-1938
Number of pages4
JournalAngewandte Chemie - International Edition
Volume40
Issue number10
DOIs
Publication statusPublished - 2001 May 18
Externally publishedYes

Keywords

  • Cuprates
  • Density functional calculations
  • Kinetics
  • Lithium
  • Reaction mechanisms

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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