Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster

Akihiro Hashikawa, Makiko Fujimoto, Yoshihito Hayashi, Hitoshi Miyasaka

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A polyoxotetradecamolybdate cluster [Mo14O38(OAc) 6]2-, which has a lacunary core of the Wells-Dawson structure, is isolated by the reduction of [Mo6O19] 2-. The Mo14 core is comprised of a mixed valence of [MoV4MoVI10], exhibiting multi-step reversible redox processes that experience both oxidation and reduction.

Original languageEnglish
Pages (from-to)12361-12363
Number of pages3
JournalChemical Communications
Volume47
Issue number45
DOIs
Publication statusPublished - 2011 Dec 7
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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