Ionic Donor–Acceptor Chain Derived from an Electron-Transfer Reaction of a Paddlewheel-Type Diruthenium(II, II) Complex and N,N′-Dicyanoquinonediimine

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Abstract

A new ionic donor–acceptor (D+A) chain compound, [{Ru2(2,6-(CF3)2PhCO2)2(p-PhPhCO2)2}DMDCNQI] (1; 2,6-(CF3)2PhCO2 =2,6-bis(trifluoromethyl)benzoate; p-PhPhCO2 =4-biphenylcarboxylate; DMDCNQI=2,5-dimethyl-N,N′-dicyanoquinonediimine) was isolated and structurally characterized. It represents the first of this type of ionic chain compounds.

Original languageEnglish
Pages (from-to)13093-13097
Number of pages5
JournalChemistry - A European Journal
Volume24
Issue number50
DOIs
Publication statusPublished - 2018 Sep 6

Keywords

  • chain structures
  • charge transfer
  • donor–acceptor systems
  • electron transfer
  • magnetic properties

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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