Ionic conductivity of [Li+@C60](PF6) in organic solvents and its electrochemical reduction to Li+@C60·

Hiroshi Ueno, Ken Kokubo, Yuji Nakamura, Kei Ohkubo, Naohiko Ikuma, Hiroshi Moriyama, Shunichi Fukuzumi, Takumi Oshimaa

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

The ionic conductivity of [Li+@C60](PF6) was measured in o-dichlorobenzene, and found to be higher than that of TBA+PF6. Electrochemical reduction of [Li+@C60](PF6) without any supporting electrolyte gave the monovalent radical anion Li+@C60·, as confirmed by the characteristic ESR signal and NIR absorption band.

Original languageEnglish
Pages (from-to)7376-7378
Number of pages3
JournalChemical Communications
Volume49
Issue number67
DOIs
Publication statusPublished - 2013 Jul 25
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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