Ion-induced transformation of magnetism in a bimetallic CuFe Prussian blue analogue

Masashi Okubo, Daisuke Asakura, Yoshifumi Mizuno, Tetsuichi Kudo, Haoshen Zhou, Atsushi Okazawa, Norimichi Kojima, Kazumichi Ikedo, Takashi Mizokawa, Itaru Honma

    Research output: Contribution to journalArticlepeer-review

    70 Citations (Scopus)

    Abstract

    Li ions for degaussing: A Prussian blue analogue with FeIII and CuII ions bridged by CN ligands underwent a ferromagnetic transition induced by ferromagnetic interactions between the Fe and Cu ions (see picture). Li ions penetrating into this ferromagnetic framework eliminated the ferromagnetic interaction and effected the formation of a paramagnetic framework. The ferromagnetism was recovered by extracting the Li ions.

    Original languageEnglish
    Pages (from-to)6269-6273
    Number of pages5
    JournalAngewandte Chemie - International Edition
    Volume50
    Issue number28
    DOIs
    Publication statusPublished - 2011 Jul 4

    Keywords

    • Mössbauer spectroscopy
    • coordination chemistry
    • electrochemistry
    • electronic structure
    • magnetic materials

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)

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