We have applied a high-resolution-electron-momentum-resolved-ion coincidence technique to the Auger emission from CF4 following the F 1s→a1* excitation and found that the Auger electron emitted from the atomic F fragment during the ultrafast dissociation is backscattered by the residual fragment CF3. We find also that more than half of the excess energy goes into the vibrational excitation of the CF3 fragment.
|Journal||Physical Review A - Atomic, Molecular, and Optical Physics|
|Publication status||Published - 2005 May 1|
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics