Intramolecular addition of benzyl anion to alkyne utilizing [1,2]-phospha-Brook rearrangement under Brønsted base catalysis

Azusa Kondoh, Ryosuke Ozawa, Takuma Aoki, Masahiro Terada

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A novel reaction system for intramolecular addition of benzyl anions to alkynes was developed by utilizing the [1,2]-phospha-Brook rearrangement under Brønsted base catalysis. The present reaction is a rare example of a catalytic addition reaction of an unstabilized benzyl anion under Brønsted base catalysis.

Original languageEnglish
Pages (from-to)7277-7281
Number of pages5
JournalOrganic and Biomolecular Chemistry
Volume15
Issue number35
DOIs
Publication statusPublished - 2017 Jan 1

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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