Internal amide-triggered cycloaromatization of maduropeptin-like nine-membered enediyne

Yutaro Norizuki, Kazuo Komano, Itaru Sato, Masahiro Hirama

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

In the Masamune-Bergman cyclization of a nine-membered non-conjugated enediyne with an internal, maduropeptin-like nucleophile, the exocyclic alkene migrated to form the nine-membered conjugated enediyne, triggered by the intramolecular addition of the amide group; final aromatized products showed up to 85% yield.

Original languageEnglish
Pages (from-to)5372-5374
Number of pages3
JournalChemical Communications
Issue number42
DOIs
Publication statusPublished - 2008 Nov 10

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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