Interfacial Synthesis of Electrically Conducting Palladium Bis(dithiolene) Complex Nanosheet

Tigmansu Pal; Tetsuya Kambe; Tetsuro Kusamoto; Maw Lin Foo; Ryota Matsuoka; Ryota Sakamoto; Hiroshi Nishihara

doi:10.1002/cplu.201500206

Interfacial Synthesis of Electrically Conducting Palladium Bis(dithiolene) Complex Nanosheet

Tigmansu Pal, Tetsuya Kambe, Tetsuro Kusamoto, Maw Lin Foo, Ryota Matsuoka, Ryota Sakamoto, Hiroshi Nishihara

Research output: Contribution to journal › Article › peer-review

97 Citations (Scopus)

Abstract

The synthesis of palladium bis(dithiolene) complex nanosheets (PdDt) possessing a kagome-type lattice structure was performed via interfacial reaction between metal salt in aqueous phase and dithiolato ligand in organic phase. The PdDt nanosheets were characterised by AFM, STM, TEM revealing flat and sheet-like morphology; IR, UV spectroscopy show the corresponding coordination connectivity between metal and ligand, followed by powder X-ray diffraction and SAED, which determined nanosheets to be structurally similar to previously reported nickel bis(dithiolene) complex nanosheets NiDt.

Original language	English
Pages (from-to)	1255-1258
Number of pages	4
Journal	ChemPlusChem
Volume	80
Issue number	8
DOIs	https://doi.org/10.1002/cplu.201500206
Publication status	Published - 2015 Aug 1
Externally published	Yes

Keywords

electrochemistry
nanostructures
synthesis design
thin films
transition metals

ASJC Scopus subject areas

Chemistry(all)

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10.1002/cplu.201500206

Cite this

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title = "Interfacial Synthesis of Electrically Conducting Palladium Bis(dithiolene) Complex Nanosheet",

abstract = "The synthesis of palladium bis(dithiolene) complex nanosheets (PdDt) possessing a kagome-type lattice structure was performed via interfacial reaction between metal salt in aqueous phase and dithiolato ligand in organic phase. The PdDt nanosheets were characterised by AFM, STM, TEM revealing flat and sheet-like morphology; IR, UV spectroscopy show the corresponding coordination connectivity between metal and ligand, followed by powder X-ray diffraction and SAED, which determined nanosheets to be structurally similar to previously reported nickel bis(dithiolene) complex nanosheets NiDt.",

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AU - Pal, Tigmansu

AU - Kambe, Tetsuya

AU - Kusamoto, Tetsuro

AU - Foo, Maw Lin

AU - Matsuoka, Ryota

AU - Sakamoto, Ryota

AU - Nishihara, Hiroshi

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AB - The synthesis of palladium bis(dithiolene) complex nanosheets (PdDt) possessing a kagome-type lattice structure was performed via interfacial reaction between metal salt in aqueous phase and dithiolato ligand in organic phase. The PdDt nanosheets were characterised by AFM, STM, TEM revealing flat and sheet-like morphology; IR, UV spectroscopy show the corresponding coordination connectivity between metal and ligand, followed by powder X-ray diffraction and SAED, which determined nanosheets to be structurally similar to previously reported nickel bis(dithiolene) complex nanosheets NiDt.

KW - electrochemistry

KW - nanostructures

KW - synthesis design

KW - thin films

KW - transition metals

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Interfacial Synthesis of Electrically Conducting Palladium Bis(dithiolene) Complex Nanosheet

Abstract

Keywords

ASJC Scopus subject areas

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