Abstract
Irradiation of a toluene solution of[Ru2(CO)6-(μ-dppm)(μ-SiTol2)] (1) in the presence of an excess of Tol2SiH2 produced a μ-silyl complex, [Ru2(CO)5(SiTol2H)-(μ-dppm)(μ-n2 -HSiTol2)] (2), which was further converted to a μ-silane complex, [{Ru(CO)2(SiTol2H)}2(μ-dppm)(μ-n2 :n2-H2SiTol2)] (3), quantitatively. Complex 3 released Tol2SiH2 in the presence of CO to regenerate 2, which finally reverted to 1 under thermal conditions. The X-ray crystal structures of 1 and 3 were determined.
| Original language | English |
|---|---|
| Pages (from-to) | 1534-1536 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 21 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2002 Apr 14 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Hashimoto, H., Hayashi, Y., Aratani, I., Kabuto, C., & Kira, M. (2002). Interconversion among μ-silylene, μ-silyl, and μ-silane diruthenium complexes in the presence of dihydrosilane. Organometallics, 21(8), 1534-1536. https://doi.org/10.1021/om0109814