Intercalation of benzenecarboxylate ions into the interlayer of hydrotalcite

Tsugio Sato, Akitsugu Okawaki

Research output: Contribution to journalArticle

52 Citations (Scopus)

Abstract

Intercalation behaviour of benzenecarboxylic acids in the interlayer of hydrotalcite was investigated by using the chemical reaction of rock-salt type magnesium aluminum oxide, Mg0.61Al0.26O, and various benzenecarboxylates in aqueous solutions at 50-70°C. Magnesium aluminum oxide hydrated and combined with benzenecarboxylate ions and hydroxyl ion competitively to form hydrotalcite-like compounds. The amount of benzenecarboxylate ions incorporated in the interlayer of hydrotalcite and the selectivity of anion uptake increased with increasing charge density of the ions.

Original languageEnglish
Pages (from-to)43-48
Number of pages6
JournalSolid State Ionics
Volume45
Issue number1-2
DOIs
Publication statusPublished - 1991 Mar

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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