Intercalation of benzenecarboxylate ions into the interlayer of hydrotalcite

Tsugio Sato, Akitsugu Okawaki

    Research output: Contribution to journalArticlepeer-review

    52 Citations (Scopus)

    Abstract

    Intercalation behaviour of benzenecarboxylic acids in the interlayer of hydrotalcite was investigated by using the chemical reaction of rock-salt type magnesium aluminum oxide, Mg0.61Al0.26O, and various benzenecarboxylates in aqueous solutions at 50-70°C. Magnesium aluminum oxide hydrated and combined with benzenecarboxylate ions and hydroxyl ion competitively to form hydrotalcite-like compounds. The amount of benzenecarboxylate ions incorporated in the interlayer of hydrotalcite and the selectivity of anion uptake increased with increasing charge density of the ions.

    Original languageEnglish
    Pages (from-to)43-48
    Number of pages6
    JournalSolid State Ionics
    Volume45
    Issue number1-2
    DOIs
    Publication statusPublished - 1991 Mar

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics

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