Insertion of carbon monoxide into an aldehyde CO double bond induced by an (η3-α-silabenzyl)carbonylmolybdenum complex

Yuto Kanno, Takashi Komuro, Hiromi Tobita

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Unusual silylcarbonylation of aldehyde through CO insertion into a CO double bond induced by a metal-silicon complex has been discovered: treatment of an (η3-α-silabenzyl)carbonylmolybdenum complex with alkylaldehydes afforded isolable O-silylated Mo-C-O three-membered-ring complexes, and one of them was subsequently converted to an η3- oxaallyl complex at room temperature through CO insertion into the metallacycle C-O bond and incorporation of a CO molecule.

Original languageEnglish
Pages (from-to)19068-19071
Number of pages4
JournalRSC Advances
Volume4
Issue number37
DOIs
Publication statusPublished - 2014

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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