Insertion of a Cationic Metallogermylene into E-H Bonds (E = H, B, Si)

Koya Inomata; Takahito Watanabe; Yoshikazu Miyazaki; Hiromi Tobita

doi:10.1021/jacs.5b08169

Insertion of a Cationic Metallogermylene into E-H Bonds (E = H, B, Si)

Koya Inomata, Takahito Watanabe, Yoshikazu Miyazaki, Hiromi Tobita

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

A cationic germylene containing tungsten and N-heterocyclic carbene units reacted with H₂ in fluorobenzene at 60 °C, resulting in its insertion into the H-H bond. It also activated the Si-H bond of ethyldimethylsilane and the B-H bond of pinacolborane at ambient temperature to give the insertion products. The latter insertion reactions against hydrosilane and hydroborane were found to be reversible.

Original language	English
Pages (from-to)	11935-11937
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	137
Issue number	37
DOIs	https://doi.org/10.1021/jacs.5b08169
Publication status	Published - 2015 Sept 23

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "A cationic germylene containing tungsten and N-heterocyclic carbene units reacted with H2 in fluorobenzene at 60 °C, resulting in its insertion into the H-H bond. It also activated the Si-H bond of ethyldimethylsilane and the B-H bond of pinacolborane at ambient temperature to give the insertion products. The latter insertion reactions against hydrosilane and hydroborane were found to be reversible.",

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AU - Miyazaki, Yoshikazu

AU - Tobita, Hiromi

PY - 2015/9/23

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AB - A cationic germylene containing tungsten and N-heterocyclic carbene units reacted with H2 in fluorobenzene at 60 °C, resulting in its insertion into the H-H bond. It also activated the Si-H bond of ethyldimethylsilane and the B-H bond of pinacolborane at ambient temperature to give the insertion products. The latter insertion reactions against hydrosilane and hydroborane were found to be reversible.

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Insertion of a Cationic Metallogermylene into E-H Bonds (E = H, B, Si)

Abstract

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