Inorganic frameworks made by combining paddle-wheel diruthenium(II, III) complexes and polyoxometalate clusters

Yuki Sawada; Yuma Yamamoto; Masaki Nishio; Wataru Kosaka; Yoshihito Hayashi; Hitoshi Miyasaka

doi:10.1246/cl.2012.212

Inorganic frameworks made by combining paddle-wheel diruthenium(II, III) complexes and polyoxometalate clusters

Yuki Sawada, Yuma Yamamoto, Masaki Nishio, Wataru Kosaka, Yoshihito Hayashi, Hitoshi Miyasaka

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The reactions of a pivalate-bridged paddle-wheel diruthenium( II, III) complex, [Ru ₂ ^II,III(piv) ₄(THF) ₂]BF ₄, with two kinds of polyoxometalates (POMs), (TBA) ₂[Mo ₆O ₁₉] and (TBA) ₃[H ₃-V ₁₀O ₂₈] (TBA: tetra-n-butylammonium cation), led to the formation of one- and two-dimensional inorganic frameworks composed of [-{Ru ₂} _n-(POM)-] ^- repeating units with n = 1 and 2, respectively.

Original language	English
Pages (from-to)	212-214
Number of pages	3
Journal	Chemistry Letters
Volume	41
Issue number	3
DOIs	https://doi.org/10.1246/cl.2012.212
Publication status	Published - 2012 Feb 27
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Inorganic frameworks made by combining paddle-wheel diruthenium(II, III) complexes and polyoxometalate clusters",

abstract = "The reactions of a pivalate-bridged paddle-wheel diruthenium( II, III) complex, [Ru 2 II,III(piv) 4(THF) 2]BF 4, with two kinds of polyoxometalates (POMs), (TBA) 2[Mo 6O 19] and (TBA) 3[H 3-V 10O 28] (TBA: tetra-n-butylammonium cation), led to the formation of one- and two-dimensional inorganic frameworks composed of [-{Ru 2} n-(POM)-] - repeating units with n = 1 and 2, respectively.",

author = "Yuki Sawada and Yuma Yamamoto and Masaki Nishio and Wataru Kosaka and Yoshihito Hayashi and Hitoshi Miyasaka",

year = "2012",

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doi = "10.1246/cl.2012.212",

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journal = "Chemistry Letters",

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T1 - Inorganic frameworks made by combining paddle-wheel diruthenium(II, III) complexes and polyoxometalate clusters

AU - Sawada, Yuki

AU - Yamamoto, Yuma

AU - Nishio, Masaki

AU - Kosaka, Wataru

AU - Hayashi, Yoshihito

AU - Miyasaka, Hitoshi

PY - 2012/2/27

Y1 - 2012/2/27

N2 - The reactions of a pivalate-bridged paddle-wheel diruthenium( II, III) complex, [Ru 2 II,III(piv) 4(THF) 2]BF 4, with two kinds of polyoxometalates (POMs), (TBA) 2[Mo 6O 19] and (TBA) 3[H 3-V 10O 28] (TBA: tetra-n-butylammonium cation), led to the formation of one- and two-dimensional inorganic frameworks composed of [-{Ru 2} n-(POM)-] - repeating units with n = 1 and 2, respectively.

AB - The reactions of a pivalate-bridged paddle-wheel diruthenium( II, III) complex, [Ru 2 II,III(piv) 4(THF) 2]BF 4, with two kinds of polyoxometalates (POMs), (TBA) 2[Mo 6O 19] and (TBA) 3[H 3-V 10O 28] (TBA: tetra-n-butylammonium cation), led to the formation of one- and two-dimensional inorganic frameworks composed of [-{Ru 2} n-(POM)-] - repeating units with n = 1 and 2, respectively.

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