Abstract
The OH stretching vibration of jet-cooled phenol-N2 in the neural and cationic ground states was observed by using infrared-ultraviolet double resonance spectroscopy and infrared photodissociation spectroscopy, respectively. The OH vibration showed a small but significant low-frequency shift of 5 cm-1 upon the cluster formation in the neutral, while the shift drastically increased up to 159 cm-1 in the cation. These results represent the direct evidence of the in-plane cluster structure, in which phenolic OH is hydrogen bonded to N2, as was proposed in the zero kinetic energy photoelectron study [S. R. Haines et al., J. Chem. Phys. 109, 9244 (1998)].
| Original language | English |
|---|---|
| Pages (from-to) | 11125-11128 |
| Number of pages | 4 |
| Journal | Journal of Chemical Physics |
| Volume | 110 |
| Issue number | 23 |
| DOIs | |
| Publication status | Published - 1999 Jun 15 |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
Fingerprint Dive into the research topics of 'Infrared spectroscopy of the phenol-N<sub>2</sub> cluster in S<sub>0</sub> and D<sub>0</sub>: Direct evidence of the in-plane structure of the cluster'. Together they form a unique fingerprint.
Cite this
Fujii, A., Miyazaki, M., Ebata, T., & Mikami, N. (1999). Infrared spectroscopy of the phenol-N2 cluster in S0 and D0: Direct evidence of the in-plane structure of the cluster. Journal of Chemical Physics, 110(23), 11125-11128. https://doi.org/10.1063/1.479055