TY - JOUR
T1 - Infrared spectroscopy of the phenol-N2 cluster in S0 and D0
T2 - Direct evidence of the in-plane structure of the cluster
AU - Fujii, Asuka
AU - Miyazaki, Mitsuhiko
AU - Ebata, Takayuki
AU - Mikami, Naohiko
PY - 1999/6/15
Y1 - 1999/6/15
N2 - The OH stretching vibration of jet-cooled phenol-N2 in the neural and cationic ground states was observed by using infrared-ultraviolet double resonance spectroscopy and infrared photodissociation spectroscopy, respectively. The OH vibration showed a small but significant low-frequency shift of 5 cm-1 upon the cluster formation in the neutral, while the shift drastically increased up to 159 cm-1 in the cation. These results represent the direct evidence of the in-plane cluster structure, in which phenolic OH is hydrogen bonded to N2, as was proposed in the zero kinetic energy photoelectron study [S. R. Haines et al., J. Chem. Phys. 109, 9244 (1998)].
AB - The OH stretching vibration of jet-cooled phenol-N2 in the neural and cationic ground states was observed by using infrared-ultraviolet double resonance spectroscopy and infrared photodissociation spectroscopy, respectively. The OH vibration showed a small but significant low-frequency shift of 5 cm-1 upon the cluster formation in the neutral, while the shift drastically increased up to 159 cm-1 in the cation. These results represent the direct evidence of the in-plane cluster structure, in which phenolic OH is hydrogen bonded to N2, as was proposed in the zero kinetic energy photoelectron study [S. R. Haines et al., J. Chem. Phys. 109, 9244 (1998)].
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U2 - 10.1063/1.479055
DO - 10.1063/1.479055
M3 - Article
AN - SCOPUS:0000946198
VL - 110
SP - 11125
EP - 11128
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 23
ER -