Infrared spectroscopic study of the acidic CH bonds in hydrated clusters of cationic pentane

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6 Citations (Scopus)

Abstract

Infrared spectroscopy of the hydrated clusters of cationic pentane, which are generated through the vacuum ultraviolet photoionization in the gas phase, is carried out to probe the acidic properties of their CH bonds. The monohydrated pentane cation forms the proton-shared structure, in which the proton of CH in cationic pentane is shared between the pentyl radical and water molecule. In the di- and trihydrated clusters, the proton of CH is completely transferred to the water moiety so that the clusters are composed of the pentyl radical and protonated water cluster. These results indicate that two water molecules are enough to cause the proton transfer from CH of cationic pentane, and thus its acidity is highly enhanced with the ionization.

Original languageEnglish
Pages (from-to)4716-4719
Number of pages4
JournalJournal of Physical Chemistry Letters
Volume8
Issue number19
DOIs
Publication statusPublished - 2017 Oct 5

ASJC Scopus subject areas

  • Materials Science(all)
  • Physical and Theoretical Chemistry

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