Infrared spectra of 13C-substituted species of solid sodium acetate at 80 K

Masato Kakihana, Masahiro Kotaka, Makoto Okamoto

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    13 Citations (Scopus)

    Abstract

    The infrared spectra (4000-300 cm-1) of CH3COONa and 13C-labeled modifications (1-13C, 2-13C, and 1,2-13C) suspended in KBr disks were measured at 80 and 290 K. Excellent resolutions were reached by recording the spectra at the low temperature. A new improved assignment was reported for the fundamentals located in the spectral regions 3100-2900 and 1500-1300 cm-1. In the former spectral region, three distinct absorption bands due to CH3-stretching modes were observed without degeneracy. In the latter spectral region, four major fundamentals were found and were reasonably assigned to the symmetric COO-stretching and CH3-deformation modes on the basis of the 13C shifts of the fundamentals.

    Original languageEnglish
    Pages (from-to)4385-4387
    Number of pages3
    JournalJournal of physical chemistry
    Volume86
    Issue number22
    DOIs
    Publication statusPublished - 1982 Jan 1

    ASJC Scopus subject areas

    • Engineering(all)
    • Physical and Theoretical Chemistry

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