Infrared emission spectra of CaF2-CaO-SiO2 melt

Shigeru Ueda, Hirotaka Koyo, Takashi Ikeda, Yoshiharu Kariya, Masafumi Maeda

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

The infrared emission spectra of CaF2-CaO-SiO2 melt were investigated by a method combining infrared emission spectroscopy and the hot-filament technique. Emission for spectra related to Si-O bond can be observed by this in situ technique. The influence of SiO2 and fluoride content on the spectrum was investigated, and the emission attributable to bonds corresponding to silicon-bridging oxygen and silicon-non bridging oxygen was discussed. Results suggest that fluoride ion dominantly substitutes for a non-bridging bond in low SiO2 concentration region. The structure of silicate was compared with calculated infrared emission of Si-F-O.

Original languageEnglish
Pages (from-to)739-743
Number of pages5
JournalIsij International
Volume40
Issue number8
DOIs
Publication statusPublished - 2000

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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