Infrared dissociation spectroscopy of the OH stretching vibration of phenol-rare gas van der Waals cluster ions

Asuka Fujii, Takahiro Sawamura, Shigeki Tanabe, Takayuki Ebata, Naohiko Mikami

Research output: Contribution to journalArticlepeer-review

76 Citations (Scopus)

Abstract

Infrared dissociation spectra of phenol-Ar and -Kr van der Waals cluster ions in supersonic free jets were observed in the absorption region of the OH stretching vibration. Both spectra showed the OH stretching vibration at 3535 ± 2 cm-1, indicating that the perturbation of the rare gases is small and the observed frequency represents that of the bare phenol ion. The vibrational frequency of the phenol ion was found to be 122 cm- smaller than that of neutral phenol.

Original languageEnglish
Pages (from-to)104-107
Number of pages4
JournalChemical Physics Letters
Volume225
Issue number1-3
DOIs
Publication statusPublished - 1994 Jul 29

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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