Influence of icosahedral clusters on crystallization of Zr 55Ni10Al7.5Cu7.5Ti 10Ta10 glassy alloy

Lj Ouyang; D. V. Louzguine; H. M. Kimura; T. Ohsuna; S. Ranganathan; A. Inoue

doi:10.4028/www.scientific.net/JMNM.18.37

Influence of icosahedral clusters on crystallization of Zr ₅₅Ni₁₀Al_7.5Cu_7.5Ti ₁₀Ta₁₀ glassy alloy

Lj Ouyang, D. V. Louzguine, H. M. Kimura, T. Ohsuna, S. Ranganathan, A. Inoue

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The crystallization behavior and phase formation in Zr₅₅Ni ₁₀Al_7.5Cu_7.5Ti₁₀Ta₁₀ metallic glass have been studied by x-ray diffraction, transmission electron microscopy and differential scanning calorimetry. Mutual addition of Ti and Ta is found to benefit the formation of the icosahedral phase in the glassy phase on heating without energy barrier for nucleation. The value of the activation energy for nucleation and growth estimated by Kissinger analysis also supports this result.

Original language	English
Pages (from-to)	37-42
Number of pages	6
Journal	Journal of Metastable and Nanocrystalline Materials
Volume	18
DOIs	https://doi.org/10.4028/www.scientific.net/JMNM.18.37
Publication status	Published - 2003

Keywords

Differential scanning calorimetry
Glassy alloy
Icosahedral
Transmission electron microscopy

ASJC Scopus subject areas

Materials Science (miscellaneous)
Materials Science(all)
Condensed Matter Physics
Physical and Theoretical Chemistry

Access to Document

10.4028/www.scientific.net/JMNM.18.37

Cite this

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title = "Influence of icosahedral clusters on crystallization of Zr 55Ni10Al7.5Cu7.5Ti 10Ta10 glassy alloy",

abstract = "The crystallization behavior and phase formation in Zr55Ni 10Al7.5Cu7.5Ti10Ta10 metallic glass have been studied by x-ray diffraction, transmission electron microscopy and differential scanning calorimetry. Mutual addition of Ti and Ta is found to benefit the formation of the icosahedral phase in the glassy phase on heating without energy barrier for nucleation. The value of the activation energy for nucleation and growth estimated by Kissinger analysis also supports this result.",

keywords = "Differential scanning calorimetry, Glassy alloy, Icosahedral, Transmission electron microscopy",

author = "Lj Ouyang and Louzguine, {D. V.} and Kimura, {H. M.} and T. Ohsuna and S. Ranganathan and A. Inoue",

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T1 - Influence of icosahedral clusters on crystallization of Zr 55Ni10Al7.5Cu7.5Ti 10Ta10 glassy alloy

AU - Ouyang, Lj

AU - Louzguine, D. V.

AU - Kimura, H. M.

AU - Ohsuna, T.

AU - Ranganathan, S.

AU - Inoue, A.

PY - 2003

Y1 - 2003

N2 - The crystallization behavior and phase formation in Zr55Ni 10Al7.5Cu7.5Ti10Ta10 metallic glass have been studied by x-ray diffraction, transmission electron microscopy and differential scanning calorimetry. Mutual addition of Ti and Ta is found to benefit the formation of the icosahedral phase in the glassy phase on heating without energy barrier for nucleation. The value of the activation energy for nucleation and growth estimated by Kissinger analysis also supports this result.

AB - The crystallization behavior and phase formation in Zr55Ni 10Al7.5Cu7.5Ti10Ta10 metallic glass have been studied by x-ray diffraction, transmission electron microscopy and differential scanning calorimetry. Mutual addition of Ti and Ta is found to benefit the formation of the icosahedral phase in the glassy phase on heating without energy barrier for nucleation. The value of the activation energy for nucleation and growth estimated by Kissinger analysis also supports this result.

KW - Differential scanning calorimetry

KW - Glassy alloy

KW - Icosahedral

KW - Transmission electron microscopy

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