Influence of diluent on radiolysis of amides in organic solution

Yumi Sugo, Yoshinobu Izumi, Yoichi Yoshida, Shigehiro Nishijima, Yuji Sasaki, Takaumi Kimura, Tsutomu Sekine, Hiroshi Kudo

Research output: Contribution to journalArticlepeer-review

66 Citations (Scopus)

Abstract

The radiolytic behavior of N,N,N′,N′-tetraoctyldiglycolamide, N,N′-dimethyl-N,N′-dioctyl-2-(3′-oxapentadecyl)malonamide, and N,N-dioctylhexanamide in n-dodecane was investigated by irradiation with γ-rays and electron pulses. The results showed n-dodecane has a sensitization effect on the radiolysis of these amides, owing mainly to a charge transfer from radical cations of n-dodecane to the amide molecules in the primary process observed in pulse radiolysis. This result was supported by the difference in the ionization potentials between n-dodecane and these amides.

Original languageEnglish
Pages (from-to)794-800
Number of pages7
JournalRadiation Physics and Chemistry
Volume76
Issue number5
DOIs
Publication statusPublished - 2007 May 1

Keywords

  • Charge transfer
  • Diglycolamide
  • Malonamide
  • Monoamide
  • Pulse radiolysis
  • Radical cation
  • n-dodecane
  • γ-radiolysis

ASJC Scopus subject areas

  • Radiation

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