Influence of casting solvents on microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene

Y. Funaki; K. Kumano; T. Nakao; H. Jinnai; H. Yoshida; K. Kimishima; K. Tsutsumi; Y. Hirokawa; T. Hashimoto

doi:10.1016/S0032-3861(99)00112-3

Influence of casting solvents on microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene

Y. Funaki, K. Kumano, T. Nakao, H. Jinnai, H. Yoshida, K. Kimishima, K. Tsutsumi, Y. Hirokawa, T. Hashimoto

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

Influences of casting solvent on the microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene films were studied by transmission electron microscopy and small-angle X-ray scattering. The variations of the structures obtained were consequences of vitrification of microdomain structures developed during the solvent casting processes. The various microphase-separated structures were properly understood by considering the Hansen's solubility parameters of the solvent and the copolymer, which quantify the polymer-solvent interactions in the system.

Original language	English
Pages (from-to)	7147-7156
Number of pages	10
Journal	Polymer
Volume	40
Issue number	25
DOIs	https://doi.org/10.1016/S0032-3861(99)00112-3
Publication status	Published - 1999 Dec
Externally published	Yes

Keywords

Casting solvent
Microphase- separated structures
Poly(2-vinylpyridine)-block-polyisoprene

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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title = "Influence of casting solvents on microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene",

abstract = "Influences of casting solvent on the microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene films were studied by transmission electron microscopy and small-angle X-ray scattering. The variations of the structures obtained were consequences of vitrification of microdomain structures developed during the solvent casting processes. The various microphase-separated structures were properly understood by considering the Hansen's solubility parameters of the solvent and the copolymer, which quantify the polymer-solvent interactions in the system.",

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author = "Y. Funaki and K. Kumano and T. Nakao and H. Jinnai and H. Yoshida and K. Kimishima and K. Tsutsumi and Y. Hirokawa and T. Hashimoto",

year = "1999",

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T1 - Influence of casting solvents on microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene

AU - Funaki, Y.

AU - Kumano, K.

AU - Nakao, T.

AU - Jinnai, H.

AU - Yoshida, H.

AU - Kimishima, K.

AU - Tsutsumi, K.

AU - Hirokawa, Y.

AU - Hashimoto, T.

PY - 1999/12

Y1 - 1999/12

N2 - Influences of casting solvent on the microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene films were studied by transmission electron microscopy and small-angle X-ray scattering. The variations of the structures obtained were consequences of vitrification of microdomain structures developed during the solvent casting processes. The various microphase-separated structures were properly understood by considering the Hansen's solubility parameters of the solvent and the copolymer, which quantify the polymer-solvent interactions in the system.

AB - Influences of casting solvent on the microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene films were studied by transmission electron microscopy and small-angle X-ray scattering. The variations of the structures obtained were consequences of vitrification of microdomain structures developed during the solvent casting processes. The various microphase-separated structures were properly understood by considering the Hansen's solubility parameters of the solvent and the copolymer, which quantify the polymer-solvent interactions in the system.

KW - Casting solvent

KW - Microphase- separated structures

KW - Poly(2-vinylpyridine)-block-polyisoprene

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