Inelastic X-ray scattering in molecular liquids and electron correlation effects

Hisashi Hayashi, Noboru Watanabe, Yasuo Udagawa

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Inelastic X-ray scattering spectra of liquid water and cyclohexane have been measured with 2 eV resolution for a momentum transfer range between 0.69 and 2.77 au at BL16A of the Photon Factory, KEK, Tsukuba. Observed spectra are transformed to the dynamic structure factor which is normalized by using the Bethe sum rule, and the static structure factor is obtained. From a comparison with extended CI calculations by the use of various basis sets, correlation effects are proved to be of vital importance in inelastic X-ray scattering.

Original languageEnglish
Pages (from-to)1052-1054
Number of pages3
JournalJournal of Synchrotron Radiation
Volume5
Issue number3
DOIs
Publication statusPublished - 1998 May 1

Keywords

  • Dynamic structure factor
  • Electron correlations
  • Inelastic X-ray scattering
  • Molecular liquids
  • Static structure factor

ASJC Scopus subject areas

  • Radiation
  • Nuclear and High Energy Physics
  • Instrumentation

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