Incarceration of (PdO) n and Pd n clusters by cage-templated synthesis of hollow silica nanoparticles

Kiyotaka Takao; Kosuke Suzuki; Tatsuya Ichijo; Sota Sato; Hiroyuki Asakura; Kentaro Teramura; Kazuo Kato; Tomonori Ohba; Takeshi Morita; Makoto Fujita

doi:10.1002/anie.201201288

Incarceration of (PdO) _n and Pd _n clusters by cage-templated synthesis of hollow silica nanoparticles

Kiyotaka Takao, Kosuke Suzuki, Tatsuya Ichijo, Sota Sato, Hiroyuki Asakura, Kentaro Teramura, Kazuo Kato, Tomonori Ohba, Takeshi Morita, Makoto Fujita

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Imprisoned palladium: A unique approach is developed to incarcerate metal clusters with strictly controlled n values within hollow silica nanoparticles. A Pd ₁₂L ₂₄ spherical complex is used as a template for the hollow silica synthesis. The incarcerated Pd ₁₂L ₂₄ core is calcinated to give (PdO) _n oxide clusters and subsequently reduced to Pd _n metal clusters within the protective hollow silica.

Original language	English
Pages (from-to)	5893-5896
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	24
DOIs	https://doi.org/10.1002/anie.201201288
Publication status	Published - 2012 Jun 11

Keywords

cage-templated synthesis
hollow silica nanoparticles
nanoclusters
palladium
self-assembly

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201201288

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Incarceration of (PdO) _n and Pd _n clusters by cage-templated synthesis of hollow silica nanoparticles. / Takao, Kiyotaka; Suzuki, Kosuke; Ichijo, Tatsuya; Sato, Sota; Asakura, Hiroyuki; Teramura, Kentaro; Kato, Kazuo; Ohba, Tomonori; Morita, Takeshi; Fujita, Makoto.

In: Angewandte Chemie - International Edition, Vol. 51, No. 24, 11.06.2012, p. 5893-5896.

Research output: Contribution to journal › Article › peer-review

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