In situ X-ray diffraction for millisecond-order dynamics of BaZrO3 nanoparticle formation in supercritical water

Akira Yoko, Makoto Akizuki, Naohisa Hirao, Shinji Kohara, Mukesh Kumar, Naoto Umezawa, Takahisa Ohno, Yoshito Oshima

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

In situ high-energy X-ray diffraction measurements were conducted to elucidate the dynamics of barium zirconate (BaZrO3) nanoparticle formation in supercritical water. Time-resolved experiments of approximately milliseconds were achieved using a continuous-flow reactor and high-energy X-ray diffraction, which allows us to probe the sample in a stainless-steel tube. The size and structure of BaZrO3 in the early stage of crystallization under supercritical conditions (400 °C, 30 MPa) and on the order of milliseconds (46-66 ms) were successfully observed. An increase in the lattice parameter of BaZrO3 owing to a decrease in the number of defect sites in the time range was observed for the first time. A first-principles calculation confirmed the relationship between Ba defects and the lattice parameter and supported the formation mechanism of BaZrO3 in which nuclei, consisting of mainly zirconium, absorb the barium ion in supercritical water during crystallization.

Original languageEnglish
Pages (from-to)746-752
Number of pages7
JournalJournal of Supercritical Fluids
Volume107
DOIs
Publication statusPublished - 2016 Jan 1
Externally publishedYes

Keywords

  • Barium zirconate nanoparticles
  • First-principles calculation
  • Formation dynamics
  • In situ X-ray diffraction
  • Supercritical water

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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