In-situ infrared spectroscopy of a photoirradiated potassium-doped C60 film

Jun Onoe, Yu Ichi Hashi, Keivan Esfarjani, Toshiki Hara, Yoshiyuki Kawazoe, Kazuo Takeuchi

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

Photodimerization between C60 molecules in a potassium-doped C60 film (a mixture of α-C60 and K3C60 phases) has been investigated using in-situ Fourier-transform (FT) infrared spectroscopy in combination with tight-binding molecular dynamics calculations. A comparison of the experimental spectrum of C60 dimers, which was found to be a main product in the photoirradiated K-doped film using an FT mass spectrometer, with the theoretical spectra for several isomers of C120 suggests that C120 species with structures similar to a bucky peanut were formed in the photoirradiated film.

Original languageEnglish
Pages (from-to)19-24
Number of pages6
JournalChemical Physics Letters
Volume315
Issue number1-2
DOIs
Publication statusPublished - 1999 Dec 17

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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