Immobilized α-diazophosphonoacetate as a versatile key precursor for palladium catalyzed indole synthesis on a polymer support

Kazuo Yamazaki; Yoshinori Kondo

doi:10.1039/b109987f

Immobilized α-diazophosphonoacetate as a versatile key precursor for palladium catalyzed indole synthesis on a polymer support

Kazuo Yamazaki, Yoshinori Kondo

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

Rh(II)-catalyzed N-H insertion reaction of immobilized α-diazophosphonoacetate with 2-haloanilines followed by Horner-Emmons reaction gave immobilized enaminoesters, which were efficiently cyclized to indoles via intramolecular palladium catalyzed reaction on a polymer support.

Original language	English
Pages (from-to)	210-211
Number of pages	2
Journal	Chemical Communications
Volume	2
Issue number	3
DOIs	https://doi.org/10.1039/b109987f
Publication status	Published - 2002 Jan 1

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Immobilized α-diazophosphonoacetate as a versatile key precursor for palladium catalyzed indole synthesis on a polymer support",

abstract = "Rh(II)-catalyzed N-H insertion reaction of immobilized α-diazophosphonoacetate with 2-haloanilines followed by Horner-Emmons reaction gave immobilized enaminoesters, which were efficiently cyclized to indoles via intramolecular palladium catalyzed reaction on a polymer support.",

author = "Kazuo Yamazaki and Yoshinori Kondo",

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AU - Yamazaki, Kazuo

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AB - Rh(II)-catalyzed N-H insertion reaction of immobilized α-diazophosphonoacetate with 2-haloanilines followed by Horner-Emmons reaction gave immobilized enaminoesters, which were efficiently cyclized to indoles via intramolecular palladium catalyzed reaction on a polymer support.

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Immobilized α-diazophosphonoacetate as a versatile key precursor for palladium catalyzed indole synthesis on a polymer support

Abstract

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