HYSCORE study on coal radicals

Tadaaki Ikoma, Osamu Ito, Shozo Tero-Kubota, Kimio Akiyama

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14 Citations (Scopus)

Abstract

Hyperfine sublevel correlation spectroscopy (HYSCORE) spectra have been measured for the radicals in eight well-characterized Argonne Premium coals and their model compounds. The broad 1H and 13C hyperfine spectra of all coals were detected at room temperature. The hyperfine structure was analyzed by the comparison with model radicals and semiempirical molecular orbital calculations. The main coal radicals are considered as two-dimensionally condensed π radicals with more than seven aromatic rings. The 13C/1H ratio of the hyperfine spectra increases with coal rank, suggesting a new index of coal rank.

Original languageEnglish
Pages (from-to)1363-1368
Number of pages6
JournalEnergy and Fuels
Volume12
Issue number6
DOIs
Publication statusPublished - 1998 Jan 1

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology

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    Ikoma, T., Ito, O., Tero-Kubota, S., & Akiyama, K. (1998). HYSCORE study on coal radicals. Energy and Fuels, 12(6), 1363-1368. https://doi.org/10.1021/ef980130h