Hydrothermal synthesis and crystal structure of a new lithium copper bismuth oxide, LiCuBiO4

Nobuhiro Kumada, Ayumi Nakamura, Akira Miura, Takahiro Takei, Masaki Azuma, Hajime Yamamoto, Eisuke Magome, Chikako Moriyoshi, Yoshihiro Kuroiwa

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

A new lithium copper bismuth oxide, LiCuBiO4 was prepared by hydrothermal reaction using NaBiO30.1*4H2O. The crystal structural model of this compound was refined by using synchrotron X-ray powder diffraction data. This bismuthate has the LiCuSbO4 related structure with the orthorhombic cell (Space group: Pnma) of a=10.9096(9), b=5.8113(5) and c=5.0073(4) Å, and the final R-factors were Rwp=4.84 and Rp=3.58%. This compound is the first example of a lithium copper bismuthate containing Bi5+. An antiferromagnetic ordering of Cu2+ moment was observed at 6 K.

Original languageEnglish
Pages (from-to)30-33
Number of pages4
JournalJournal of Solid State Chemistry
Volume245
DOIs
Publication statusPublished - 2017 Jan 1
Externally publishedYes

Keywords

  • Bismuth oxide
  • Hydrothermal reaction, Crystal structure, Magnetic property

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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