Hydrogenolysis of tetrahydrofuran-2-carboxylic acid over tungsten-modified rhodium catalyst

Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Catalysts for reduction of tetrahydrofuran-2-carboxylic acid (THFCA), which can be synthesized from furfural via oxidation and hydrogenation, were explored among the combinations of noble metal and reducible metal oxide supported on SiO2. Rh-WOx/SiO2 catalysts showed activity in C-O hydrogenolysis at 2-position of THFCA (to δ-valerolactone and 5-hydroxyvaleric acid) and higher yield ratio of these C-O hydrogenolysis products to carboxylic acid hydrogenation products than other bimetallic catalysts. The activity of Rh-WOx/SiO2 catalysts was highest at W/Rh = 0.25 mol/mol. XRD, TPR, CO adsorption and XAFS characterizations showed that the Rh-WOx/SiO2 (W/Rh = 0.25) catalyst contained Rh metal particles with surface modification with isolated W2+ oxide species. The mechanism that hydride-like species formed on Rh atom attacks the C atom at the α-position (2-position) of adsorbed carboxylate on W atom is proposed based on the similar kinetics and similar catalyst structure to Rh-MOx/SiO2 (M = Re, Mo) which is known to be active in THFA hydrogenolysis to 1,5-pentanediol.

Original languageEnglish
Article number117723
JournalApplied Catalysis A: General
Volume602
DOIs
Publication statusPublished - 2020 Jul 25

Keywords

  • Carboxylic acid
  • Hydrogenolysis
  • Rhodium
  • Ring opening
  • Tungsten

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

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