Hydrogen production from methane by using composite-type oxygen permeable membranes

Hitoshi Takamura; Masayuki Ogawa; Yusuke Aizumi; Atsunori Kamegawa; Masuo Okada

Hydrogen production from methane by using composite-type oxygen permeable membranes

Hitoshi Takamura, Masayuki Ogawa, Yusuke Aizumi, Atsunori Kamegawa, Masuo Okada

Research output: Contribution to journal › Conference article › peer-review

Abstract

This paper describes preparation and methane reforming characteristics of a proto-type reformer based on a composite-type oxygen permeable membrane. The tape-cast membrane of Sm-doped CeO₂ - 15 vol% MnFe₂O ₄ composite was combined with a ferric stainless steel separator with a same thermal expansion coefficient. For the reformer module, high CH ₄ conversion, CO and H₂ selectivity of 96%, 84%, and 89% were achieved, respectively. Based on C, H, and O balances, oxygen permeation flux was found to be 5.7 μmol/cm² s. Joule heat caused by oxygen permeation was estimated to be approximately 17.5 W, and this covered most part of heat required for reforming reactions.

Original language	English
Pages (from-to)	117-121
Number of pages	5
Journal	Materials Research Society Symposium Proceedings
Volume	885
Publication status	Published - 2006 Aug 23
Event	2005 MRS Fall Meeting - Boston, MA, United States Duration: 2005 Nov 28 → 2005 Dec 2

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Cite this

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title = "Hydrogen production from methane by using composite-type oxygen permeable membranes",

abstract = "This paper describes preparation and methane reforming characteristics of a proto-type reformer based on a composite-type oxygen permeable membrane. The tape-cast membrane of Sm-doped CeO2 - 15 vol% MnFe2O 4 composite was combined with a ferric stainless steel separator with a same thermal expansion coefficient. For the reformer module, high CH 4 conversion, CO and H2 selectivity of 96%, 84%, and 89% were achieved, respectively. Based on C, H, and O balances, oxygen permeation flux was found to be 5.7 μmol/cm2 s. Joule heat caused by oxygen permeation was estimated to be approximately 17.5 W, and this covered most part of heat required for reforming reactions.",

author = "Hitoshi Takamura and Masayuki Ogawa and Yusuke Aizumi and Atsunori Kamegawa and Masuo Okada",

year = "2006",

month = aug,

day = "23",

language = "English",

volume = "885",

pages = "117--121",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

publisher = "Materials Research Society",

note = "2005 MRS Fall Meeting ; Conference date: 28-11-2005 Through 02-12-2005",

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TY - JOUR

T1 - Hydrogen production from methane by using composite-type oxygen permeable membranes

AU - Takamura, Hitoshi

AU - Ogawa, Masayuki

AU - Aizumi, Yusuke

AU - Kamegawa, Atsunori

AU - Okada, Masuo

PY - 2006/8/23

Y1 - 2006/8/23

N2 - This paper describes preparation and methane reforming characteristics of a proto-type reformer based on a composite-type oxygen permeable membrane. The tape-cast membrane of Sm-doped CeO2 - 15 vol% MnFe2O 4 composite was combined with a ferric stainless steel separator with a same thermal expansion coefficient. For the reformer module, high CH 4 conversion, CO and H2 selectivity of 96%, 84%, and 89% were achieved, respectively. Based on C, H, and O balances, oxygen permeation flux was found to be 5.7 μmol/cm2 s. Joule heat caused by oxygen permeation was estimated to be approximately 17.5 W, and this covered most part of heat required for reforming reactions.

AB - This paper describes preparation and methane reforming characteristics of a proto-type reformer based on a composite-type oxygen permeable membrane. The tape-cast membrane of Sm-doped CeO2 - 15 vol% MnFe2O 4 composite was combined with a ferric stainless steel separator with a same thermal expansion coefficient. For the reformer module, high CH 4 conversion, CO and H2 selectivity of 96%, 84%, and 89% were achieved, respectively. Based on C, H, and O balances, oxygen permeation flux was found to be 5.7 μmol/cm2 s. Joule heat caused by oxygen permeation was estimated to be approximately 17.5 W, and this covered most part of heat required for reforming reactions.

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UR - http://www.scopus.com/inward/citedby.url?scp=33747333922&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:33747333922

VL - 885

SP - 117

EP - 121

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

SN - 0272-9172

T2 - 2005 MRS Fall Meeting

Y2 - 28 November 2005 through 2 December 2005

ER -

Hydrogen production from methane by using composite-type oxygen permeable membranes

Abstract

ASJC Scopus subject areas

UN SDGs

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