Hydrogen permeation of the Zr65Al7.5Ni10Cu12.5Pd5 alloy in three different microstructures

Shin Ichi Yamaura, Shuhei Nakata, Hisamichi Kimura, Akihisa Inoue

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    22 Citations (Scopus)

    Abstract

    We have investigated the hydrogen permeation of the melt-spun Zr65Al7.5Ni10Cu12.5Pd5 alloy in the supercooled liquid, the quasi-crystalline particle-dispersed glassy and the crystalline states. The hydrogen permeability of this alloy is highest in the supercooled liquid state and is lowest in the crystalline state, compared among the three different structures. The hydrogen permeability of the melt-spun alloys consisting of quasi-crystalline particles-dispersed in the glassy state is intermediate between the single phase glassy, and the crystalline alloys. This is presumably because the Zr content in the residual glassy phase decreases after the primary precipitation of the icosahedral-phase (i-phase), resulting in a decrease in the hydrogen permeability.

    Original languageEnglish
    Pages (from-to)126-130
    Number of pages5
    JournalJournal of Membrane Science
    Volume291
    Issue number1-2
    DOIs
    Publication statusPublished - 2007 Mar 15

    Keywords

    • Amorphous materials
    • Liquid quenching
    • Quasi-crystals

    ASJC Scopus subject areas

    • Biochemistry
    • Materials Science(all)
    • Physical and Theoretical Chemistry
    • Filtration and Separation

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