Hydrogen generation from ethanol in supercritical water without catalyst

Toshihiko Arita, Koichi Nakahara, Kenzo Nagami, Okitsugu Kajimoto

Research output: Contribution to journalArticlepeer-review

85 Citations (Scopus)

Abstract

Without oxidizing reagents or catalysts, ethanol was smoothly converted to CH3CHO and H2 in supercritical water at 450-500°C. CH3CHO was further decomposed into CH4 and CO instead of being oxidized into acetic acid. These features suggest the direct participation of water molecules in the ethanol dehydrogenation.

Original languageEnglish
Pages (from-to)1083-1086
Number of pages4
JournalTetrahedron Letters
Volume44
Issue number5
DOIs
Publication statusPublished - 2003 Jan 27
Externally publishedYes

Keywords

  • Decomposition
  • Dehydroxylation
  • Ethanol
  • Oxidation
  • Supercritical water
  • Wall effect

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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