Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: Synthesis, structures and multi-centre bonding interactions at the M-Si-H-Si four-membered ring

Hisako Hashimoto, Katsuto Komura, Takatoshi Ishizaki, Yuto Odagiri, Hiromi Tobita

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Hydrogen-bridged bis(silylene) complexes of ruthenium and iron were synthesized as the first examples of this type containing Group 8 metals and their rare four-membered ring structures and multi-center bonding interactions at the M-Si-H-Si moiety were clarified by NMR spectroscopy, X-ray crystallography and theoretical calculations.

Original languageEnglish
Pages (from-to)8701-8704
Number of pages4
JournalDalton Transactions
Volume46
Issue number27
DOIs
Publication statusPublished - 2017

ASJC Scopus subject areas

  • Inorganic Chemistry

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