Hydrogen-bonded supramolecular (2,2′-bi-1H-benzimidazole)(2-(2-1H- benzimidazolyl)-1H-benzimidazolium+)2(Cl-) as an electron donor in a TCNQ complex

Tomoyuki Akutagawa; Tatsuo Hasegawa; Takayoshi Nakamura; Gunzi Saito

doi:10.1039/b210879h

Hydrogen-bonded supramolecular (2,2′-bi-1H-benzimidazole)(2-(2-1H- benzimidazolyl)-1H-benzimidazolium⁺)₂(Cl-) as an electron donor in a TCNQ complex

Tomoyuki Akutagawa, Tatsuo Hasegawa, Takayoshi Nakamura, Gunzi Saito

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Hydrogen-bonded supramolecular (H2BBIM)(H3BBIM⁺) ₂(Cl-)₂ (H2BBIM = 2,2′-bi-1H-benzimidazole; H3BBIM⁺ = 2-(2-1H-benzimidazolyl)-1H-benzimidazolium) acted as a π-electron donor in a charge-transfer complex with 7,7,8,8-tetracyano-p- quinodimethane (TCNQ). Charge-transfer interactions were confirmed between H2BBIM and TCNQ in the mixed-stack column.

Original language	English
Pages (from-to)	54-57
Number of pages	4
Journal	CrystEngComm
Volume	5
DOIs	https://doi.org/10.1039/b210879h
Publication status	Published - 2003 Jan 20
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Hydrogen-bonded supramolecular (2,2′-bi-1H-benzimidazole)(2-(2-1H- benzimidazolyl)-1H-benzimidazolium+)2(Cl-) as an electron donor in a TCNQ complex",

abstract = "Hydrogen-bonded supramolecular (H2BBIM)(H3BBIM+) 2(Cl-)2 (H2BBIM = 2,2′-bi-1H-benzimidazole; H3BBIM+ = 2-(2-1H-benzimidazolyl)-1H-benzimidazolium) acted as a π-electron donor in a charge-transfer complex with 7,7,8,8-tetracyano-p- quinodimethane (TCNQ). Charge-transfer interactions were confirmed between H2BBIM and TCNQ in the mixed-stack column.",

author = "Tomoyuki Akutagawa and Tatsuo Hasegawa and Takayoshi Nakamura and Gunzi Saito",

year = "2003",

month = jan,

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doi = "10.1039/b210879h",

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T1 - Hydrogen-bonded supramolecular (2,2′-bi-1H-benzimidazole)(2-(2-1H- benzimidazolyl)-1H-benzimidazolium+)2(Cl-) as an electron donor in a TCNQ complex

AU - Akutagawa, Tomoyuki

AU - Hasegawa, Tatsuo

AU - Nakamura, Takayoshi

AU - Saito, Gunzi

PY - 2003/1/20

Y1 - 2003/1/20

N2 - Hydrogen-bonded supramolecular (H2BBIM)(H3BBIM+) 2(Cl-)2 (H2BBIM = 2,2′-bi-1H-benzimidazole; H3BBIM+ = 2-(2-1H-benzimidazolyl)-1H-benzimidazolium) acted as a π-electron donor in a charge-transfer complex with 7,7,8,8-tetracyano-p- quinodimethane (TCNQ). Charge-transfer interactions were confirmed between H2BBIM and TCNQ in the mixed-stack column.

AB - Hydrogen-bonded supramolecular (H2BBIM)(H3BBIM+) 2(Cl-)2 (H2BBIM = 2,2′-bi-1H-benzimidazole; H3BBIM+ = 2-(2-1H-benzimidazolyl)-1H-benzimidazolium) acted as a π-electron donor in a charge-transfer complex with 7,7,8,8-tetracyano-p- quinodimethane (TCNQ). Charge-transfer interactions were confirmed between H2BBIM and TCNQ in the mixed-stack column.

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Hydrogen-bonded supramolecular (2,2′-bi-1H-benzimidazole)(2-(2-1H- benzimidazolyl)-1H-benzimidazolium⁺)₂(Cl-) as an electron donor in a TCNQ complex

Abstract

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