Hybrid Materials Composed of Organic Radicals and Ru Dimers

Research output: Chapter in Book/Report/Conference proceedingChapter

1 Citation (Scopus)

Abstract

Assemblies of organic radical ligands with paddlewheel-type carboxylate-bridged diruthenium complexes ([ Ru2II, II ] with S = 1 and [ Ru2II, III ]+ with S = 3/2) provide magnetic networks or metal-organic frameworks (MOFs). They often produce long-range ordered magnets with a relatively high TC or TN (>100 K). The key to obtaining strong exchange between radical spins and [Ru2] spins is to tune the dπ-pπ orbital interactions gained by charge transfers in the assemblies.

Original languageEnglish
Title of host publicationMaterials and Energy
PublisherWorld Scientific Publishing Co. Pte Ltd
Pages169-205
Number of pages37
DOIs
Publication statusPublished - 2018 Jan 1

Publication series

NameMaterials and Energy
Volume4
ISSN (Print)2335-6596
ISSN (Electronic)2335-660X

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Renewable Energy, Sustainability and the Environment
  • Materials Science (miscellaneous)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

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  • Cite this

    Miyasaka, H. (2018). Hybrid Materials Composed of Organic Radicals and Ru Dimers. In Materials and Energy (pp. 169-205). (Materials and Energy; Vol. 4). World Scientific Publishing Co. Pte Ltd. https://doi.org/10.1142/9789813230200_0004