Abstract
Two novel homoleptic diazaporphyrinato lanthanide sandwich complexes M 2(DAP)3 [M = Ce (1), Eu (2); DAP= 2,8,12,18-tetraethyl-3, 7,13,17-tetramethyl-5,15-diazaporphyrinate] were synthesized by a one-pot reaction of the corresponding M(acac)3·-nH2O (acac = acetylacetonate) with metal-free D2h type diazaporphyrin, H 2DAP. The spectroscopic and electrochemical properties are compared with those of complexes based on D2h symmetry porphyrin ligands.
Original language | English |
---|---|
Pages (from-to) | 8242-8244 |
Number of pages | 3 |
Journal | Inorganic chemistry |
Volume | 43 |
Issue number | 26 |
DOIs | |
Publication status | Published - 2004 Dec 27 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry