Homoleptic lanthanide triple-deckers of 5,15-diazaporphyrin with D 2h symmetry

Na Pan, Yongzhong Bian, Takamitsu Fukuda, Masaki Yokoyama, Renjie Li, Saburo Neya, Jianzhuang Jiang, Nagao Kobayashi

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)

Abstract

Two novel homoleptic diazaporphyrinato lanthanide sandwich complexes M 2(DAP)3 [M = Ce (1), Eu (2); DAP= 2,8,12,18-tetraethyl-3, 7,13,17-tetramethyl-5,15-diazaporphyrinate] were synthesized by a one-pot reaction of the corresponding M(acac)3·-nH2O (acac = acetylacetonate) with metal-free D2h type diazaporphyrin, H 2DAP. The spectroscopic and electrochemical properties are compared with those of complexes based on D2h symmetry porphyrin ligands.

Original languageEnglish
Pages (from-to)8242-8244
Number of pages3
JournalInorganic chemistry
Volume43
Issue number26
DOIs
Publication statusPublished - 2004 Dec 27

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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