Highly enantioselective intramolecular aza-spiroannulation onto indoles using chiral rhodium catalysis: Asymmetric entry to the spiro-β-lactam core of chartellines

Shigeki Sato, Masatoshi Shibuya, Naoki Kanoh, Yoshiharu Iwabuchi

Research output: Contribution to journalArticlepeer-review

73 Citations (Scopus)

Abstract

A versatile, highly enantiocontrolled entry to the spiro-β-lactam core of chartellines has been developed by expanding the scope of oxidative nitrogen atom transfer methodology based on chiral Rh-nitrenoid species.

Original languageEnglish
Pages (from-to)6264-6266
Number of pages3
JournalChemical Communications
Issue number41
DOIs
Publication statusPublished - 2009 Oct 19

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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